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Engineering of modern film-forming products

Some basic information about the module

Cycle of education: 2022/2023

The name of the faculty organization unit: The faculty Chemistry

The name of the field of study: Chemical Technology

The area of study: technical sciences

The profile of studing:

The level of study: second degree study

Type of study: full time

discipline specialities : Technology of medicinal products, Chemical analysis in industry and environment , Organic and polymer technology, Polymer materials engineering, Product and ecological process engineering

The degree after graduating from university: Master of Science (MSc)

The name of the module department : Department of Polymers and Biopolymers

The code of the module: 15635

The module status: mandatory for the speciality Product and ecological process engineering

The position in the studies teaching programme: sem: 2 / W15 L30 / 3 ECTS / Z

The language of the lecture: Polish

The name of the coordinator: Barbara Pilch-Pitera, DSc, PhD

The aim of studying and bibliography

The main aim of study: Introduction with preparation, properties and application of coating-forming materials

The general information about the module: The module takes place in the second semester, includes 15 hours of lecture and 30 hours laboratory. Lectures are conducted in the form of Power Point presentations with elements of Prezi. The module ends with a final test.

Teaching materials: instrukcje laboratoryjne

others: Normy przedmiotowe dotyczące farb i lakierów

Bibliography required to complete the module
Bibliography used during lectures
1 Ochrimienko I.S., Wierchołancew W.W. Chemia i technologia substancji błonotwórczych WNT. 1982
2 Spychaj T., Spychaj S. Farby i kleje wodorozcieńczalne WNT. 1996
3 Praca zbiorowa pod red. Prociak. A., Rokicki G., Ryszkowska J. Materiały poliuretanowe: Kozakiewicz J., Pilch-Pitera B., Zetkova K., Poliuretanowe materiały powłokotwórcze PWN. 2014
4 Z Florjańczyk, S. Penczek Chemia polimerów t 2: T. Spychaj: polimery powłokotwórcze Oficyna Wydawnicza Politechniki Warszawskiej. 2002
5 Spirou E. Powder coating chemistry and technology Vincenz Network. 2012
6 Pilch-Pitera B. FARBY I LAKIERY PROSZKOWE: otrzymywanie, formowanie, nanoszenie i ocena właściwości Oficyna Wydawnicza Politechniki Rzeszowskiej. 2015
7 M. Zubielewicz, E. Kamińska-Tarnawska Pigmenty i wypełniacze Instytut Inżynierii Materiałów Polimerowych i Barwników, Toruń. 2013
Bibliography to self-study
1 Publikacje naukowe poświęcone tematyce farb i lakierów dostępne w czytelni PRz (np. Farby i lakiery, Lakiernictwo przemysłowe, Polimery, Ochrona przed korozją) .

Basic requirements in category knowledge/skills/social competences

Formal requirements: Registration for the second semester.

Basic requirements in category knowledge: Has knowledge on polymer chemistry and technology as well as testing methods for polymer materials.

Basic requirements in category skills: Has a laboratory skill in chemistry and skill at performing calculations and interpretation of results.

Basic requirements in category social competences: Knows safety and fire protection regulation in chemical laboratory. Capable of working in team and individually.

Module outcomes

MEK The student who completed the module Types of classes / teaching methods leading to achieving a given outcome of teaching Methods of verifying every mentioned outcome of teaching Relationships with KEK Relationships with PRK
01 Has knowledge of the types of binders used in modern film-forming products lecture pass the written K_W05+++
K_W09+++
P7S_WG
02 Draws chemical formulas and technological schemes of basic binder substances. Selects the appropriate synthesis parameters of binder substances. lecture pass the written K_W05+++
K_W07++
P7S_WG
03 Has knowledge of auxiliary substances used in modern film-forming products lecture pass the written K_W05+++
K_W07++
K_W09+
P7S_WG
04 Can choose the right type of modern film-forming product to the type of substrate and coating performance requirements posed lecture pass the written K_W07+
K_W09+++
K_U08++
K_U10+++
P7S_UW
P7S_WG
05 Has knowledge about the technology of different types of modern film-forming products lecture, laboratory pass the written, observation of performance K_W05+++
K_W07+++
K_W09+++
P7S_WG
06 Based on the acquired knowledge, he is able to synthesize a binder and produce a modern film-forming product on a laboratory scale laboratory observation of performance, report writting K_W05++
K_W07+++
K_U08+++
K_K02+++
P7S_KO
P7S_UW
P7S_WG
07 Based on the acquired knowledge and on the basis of physico-chemical properties of the product is able to assess it for suitability as a coating-forming material lecture, laboratory pass the written, observation of performance, written report K_U08+++
K_U09+++
K_K02+++
P7S_KO
P7S_UO
P7S_UW
08 Able to work in a team carrying out experiments involving chemical compounds as a potential of coating-forming materials on a laboratory scale laboratory observation of performance K_K02+++
P7S_KO

Attention: Depending on the epidemic situation, verification of the achieved learning outcomes specified in the study program, in particular credits and examinations at the end of specific classes, can be implemented remotely (real-time meetings).

The syllabus of the module

Sem. TK The content realized in MEK
2 TK01 Types of binder used in moderm film-forming products. W01 MEK01
2 TK02 Natural and synthetic polymers used in modern film-forming products (visualization of chemical structures as well as synthesis and modification reaction of most common used polymers; vinyl polymers, acrylics, polyurethanes, epoxy, polyester, polysiloxane, phenol-formaldehyde resins, urea, melamine, hydrocarbon). W02-W03 MEK01 MEK02 MEK04
2 TK03 The excipients used in the modern film-forming products (crosslinking catalysts, driers, pigments, flow control agents, degassing agents, deposition agents, matting agents, improved selected properties such as impact resistance, storage stability, suitable of specific properties such as antibacterial, anticorrosive, anti-graffiti, antistatic, conductivity, hydrophobicity) W04-W05 MEK03
2 TK04 Manufacturing and applications of modern waterborne film-forming products (polyurethane ionomer dispersions, acrylic, vinyl), presentation of the technological schemes with the use of MS Visio Profesional. W06 MEK05
2 TK05 Powder coatings. Technology of production and modification of powder coatings, presentation of technological schemes using the MS Visio Profesional software. W07 MEK05
2 TK06 Solventborne and high-solid coatings. Technology of producing modern solventborne and high-solid products, presentation of the technological schemes with the use of MS Visio Profesional. W08 MEK05
2 TK07 Methods for preparing substrates under application of film-forming products W09 MEK04
2 TK08 Techniques for applying film-forming products. W010 MEK05
2 TK09 Drying of the film-forming products W011 MEK04
2 TK10 Methods for evaluation of the quality of film-forming products and coatings W012-W013 MEK07
2 TK11 Aging and stabilization of polymer coatings. Elements of English terminology relating to lacquers, paints and coatings. W014-W015 MEK04
2 TK12 1.Synthesis of the air drying modified alkyd resin. 2. Manufacturing of the thermosetting powder coatings. 3. Manufacturing of anticorrosive high-solid paints. 4. Manufacturing of the latex vinyl-acrylic paints. 5. Manufacturing of pigment concentrate. 6. Evaluation of selected properties of the film-forming products obtained in exercise 1-5 (e.g. viscosity, solid content , flow, opacity, degree of dispersion of pigments), and final coatings obtained from them in the uncured state (thickness, degree of drying), and after curing (surface properties based on the measurement of contact angle (hydrophobicity, oleophobicity), chemical resistance (resistance to solvents and oils), thickness, gloss, and mechanical properties (impact resistance, elasticity, cupping, hardness, scratch and abrasion resistance, adhesion to the substrate) L01-L05 MEK01 MEK02 MEK03 MEK05 MEK06 MEK07 MEK08

The student's effort

The type of classes The work before classes The participation in classes The work after classes
Lecture (sem. 2) contact hours: 15.00 hours/sem.
complementing/reading through notes: 3.00 hours/sem.
Studying the recommended bibliography: 5.00 hours/sem.
Laboratory (sem. 2) The preparation for a Laboratory: 3.00 hours/sem.
The preparation for a test: 10.00 hours/sem.
contact hours: 30.00 hours/sem.
Finishing/Making the report: 5.00 hours/sem.
Advice (sem. 2) The participation in Advice: 3.00 hours/sem.
Credit (sem. 2) The preparation for a Credit: 15.00 hours/sem.
The written credit: 1.00 hours/sem.

The way of giving the component module grades and the final grade

The type of classes The way of giving the final grade
Lecture Written test of the issues presented in the lecture. The range of % points suit the assessments: 50-54,9% rating -3,0 (2,75), 55 - 59,9%rating 3,0, 60 - 64,9% rating +3 (3,25), 65-69,9% rating 3,5, 70-74,9% rating -4 (3,75), 75-79,9% rating 4,0, 80-84,9% rating +4 (4,25), 85-89,9% rating 4,5, 90-94,9% rating -5 (4,75), over 95% rating 5,0.
Laboratory Student must perform all of the planed experiments, prepare and pass written reports (4 written reports), pass tests from theoretical information connected with exepriments.The range of % points suit the assessments is the same as the written test from the lecture.
The final grade Final grade (K): K = 0,5 w L + 0,5 w Z; where: L, Z - positive evaluation of the lab and lecture; w - factor related to the time of credit, w= 1.0 first term, w = 0.9 second term , w = 0.8 third term.

Sample problems

Required during the exam/when receiving the credit
(-)

Realized during classes/laboratories/projects
(-)

Others
(-)

Can a student use any teaching aids during the exam/when receiving the credit : no

The contents of the module are associated with the research profile: yes

1 B. Pilch-Pitera; K. Pojnar Correlation between the Chemical Structure of (Meth)Acrylic Monomers and the Properties of Powder Clear Coatings Based on the Polyacrylate Resins 2024
2 D. Czachor-Jadacka; B. Pilch-Pitera Blokowane poliizocyjaniany o zwiększonej funkcyjności oraz sposób wytwarzania blokowanych poliizocyjanianów o zwiększonej funkcyjności 2024
3 K. Biller; D. Czachor-Jadacka; B. Pilch-Pitera Recent development advances in bio-based powder coatings: a review 2024
4 M. Kędzierski; M. Kisiel; B. Pilch-Pitera; K. Pojnar; A. Zioło UV-cured powder transparent coatings based on oligo(meth)acrylic resins 2024
5 R. Patil; B. Pilch-Pitera; K. Pojnar Progress in the development of acrylic resin-based powder coatings – an overview 2024
6 Ł. Byczyński; D. Czachor-Jadacka; M. Kisiel; B. Mossety-Leszczak; B. Pilch-Pitera; K. Pojnar; M. Walczak; J. Wojturska Poliuretanowy lakier proszkowy oraz sposób wytwarzania poliuretanowego lakieru proszkowego 2024
7 Ł. Byczyński; E. Ciszkowicz; D. Czachor-Jadacka; M. Kisiel; B. Mossety-Leszczak; B. Pilch-Pitera; M. Walczak; J. Wojturska Wodna dyspersja kationomerów uretanowo-akrylowych, sposób wytwarzania wodnej dyspersji kationomerów uretanowo-akrylowych oraz sposób wytwarzania fotoutwardzalnej powłoki z wykorzystaniem tej wodnej dyspersji 2024
8 Ł. Florczak; B. Pilch-Pitera; K. Pojnar; N. Roś Low-temperature powder paint modified with graphene oxide 2024
9 D. Czachor-Jadacka; B. Pilch-Pitera Niskotemperaturowe powłoki proszkowe otwierają nowe możliwości 2023
10 D. Czachor-Jadacka; T. Jomin; M. Kisiel; B. Pilch-Pitera Polyurethane powder coatings with low curing temperature: Research on the effect of chemical structure of crosslinking agent on the properties of coatings 2023
11 B. Pilch-Pitera Studia podyplomowe \"Farby i lakiery proszkowe – technologia wytwarzania, aplikacja, zastosowanie\" 2022
12 D. Czachor-Jadacka; B. Pilch-Pitera; K. Pojnar Lakiery proszkowe na bazie modyfikowanych żywic akrylowych 2022
13 D. Czachor-Jadacka; Ł. Florczak; B. Pilch-Pitera; K. Pojnar Właściwości ochronne niskotemperaturowych poliuretanowych lakierów proszkowych na bazie żywic akrylowych 2022
14 J. Karaś; M. Kisiel; B. Mossety-Leszczak; B. Pilch-Pitera; M. Włodarska; W. Zając The application of liquid crystalline epoxy resin for forming hybrid powder coatings 2022
15 Ł. Byczyński; A. Kramek; B. Pilch-Pitera; K. Pojnar; M. Walczak; W. Zając Polyacrylate resins containing fluoroalkyl groups for powder clear coatings 2022
16 Ł. Byczyński; B. Pilch-Pitera; J. Prejzner Kompozycja wodorozcieńczalnego tuszu do cyfrowego druku na tekstyliach, sposób jego otrzymywania oraz sposób wykonywania nadruku tą kompozycją 2022
17 Ł. Byczyński; D. Czachor-Jadacka; B. Pilch-Pitera; J. Wojturska; J. Wojturski; P. Wrona Farba proszkowa 2022
18 Ł. Byczyński; P. Król; B. Pilch-Pitera; J. Wojturska Sposób wytwarzania blokowanych poliizocyjanianów do poliuretanowych powłok proszkowych 2022
19 A. Bielaska; M. Bosek; M. Kracik; T. Matłosz; M. Nawrocki; B. Pilch-Pitera Sposób wykonywania trwałego nadruku struktur przestrzennych na płaskich powierzchniach 2021
20 D. Czachor-Jadacka; B. Pilch-Pitera Progress in development of UV curable powder coatings 2021
21 D. Czachor-Jadacka; J. Gumieniak; M. Kisiel; B. Pilch-Pitera Hydrophobic UV-Curable Powder Clear Coatings: Study on the Synthesis of New Crosslinking Agents Based on Raw Materials Derived from Renewable Sources 2021
22 D. Czachor-Jadacka; Ł. Florczak; B. Pilch-Pitera Właściwości ochronne niskotemperaturowych poliuretanowych lakierów proszkowych o zwiększonej hydrofobowości 2021
23 Ł. Byczyński; D. Czachor-Jadacka; M. Kisiel; B. Pilch-Pitera; A. Zioło Hydrophobic polyurethane powder clear coatings with lower curing temperature: Study on the synthesis of new blocked polyisocyanates 2021
24 Ł. Byczyński; P. Król; B. Pilch-Pitera; J. Wojturska Blokowane poliizocyjaniany, ich zastosowanie oraz poliuretanowe lakiery proszkowe 2021
25 Ł. Byczyński; P. Król; B. Pilch-Pitera; J. Wojturska Blokowane poliizocyjaniany, sposób ich wytwarzania i zastosowanie 2021
26 M. Dębowski; Z. Florjańczyk; A. Iuliano; S. Kowalczyk; M. Mazurek-Budzyńska; P. Parzuchowski; B. Pilch-Pitera; A. Plichta; G. Rokicki; D. Wołosz Polycarbonate-based polyurethane - attractive materials for adhesives, binders and sealants production 2020
27 Ł. Byczyński; M. Dutkiewicz; R. Januszewski; B. Pilch-Pitera; P. Wrona Epoxy coatings with increased hydrophobicity modified by isocyanurate containing siloxane 2020
28 Ł. Byczyński; Z. Florjańczyk; M. Heneczkowski; R. Oliwa; B. Pilch-Pitera; A. Plichta; G. Rokicki; J. Wadas Synthesis and characterization of one-component, moisture curing polyurethane adhesive based on Rokopol D2002 2020
29 Ł. Byczyński; D. Czachor; Ł. Florczak; K. Kowalczyk; E. Pavlova; B. Pilch-Pitera; J. Wojturski Conductive polyurethane-based powder clear coatings modified with carbon nanotubes 2019