The aim of studying and bibliography

The main aim of study: To introduce the students obtain knowledge in the scope of techniques of separation and analytes enrichment, extraction of analytes from environment samples and illustrate the apparatus these processes characteristics.

The general information about the module: Separation and analytes enrichment. Techniques of analytes extraction. Classification of extraction systems. Liquid-liquid extraction. Liquid-solid extraction. Leaching. Solid phase extraction. Supercritical Fluid Extraction. Ion-exchange chromatography. Ion-exchangers. Application of ion-exchange chromatography for separation and concentration of analytes. Thin-layer chromatography (TLC). Gas chromatography (GC) and liquid chromatography (LC). High performance liquid chromatography (HPLC). Coupled techniques (HPLC-FIA- -MS, GC-FIA-MS). Adsorption. Partition and classification of solid adsorbent. Absorption. Precipitation and coprecipitation. Coprecipitation of analytes on supports. Electrolytic precipitation. Volatility of substance. Distillation. Rectification. Mineralization. Electrolysis. Electrophoresis. Dialysis. Electrodialysis. Osmosis. Membrane techniques. Micellar techniques. Crystallization. Filtration. Fluidization. Centrifugation and ultracentrifugation. Sedimentation. Flotation. Molecular sieves. Others techniques of separation and enrichment of analytes. Examples of application of mentioned methods. Apparatus, devices and equipment for implementation of separation processes and preconcentration operation of analytes.

Teaching materials: Instrukcje do zajęć laboratoryjnych wraz z opracowanym wstępem teoretycznym

others: Dostępne wybrane materiały dydaktyczne z wykładu

Bibliography required to complete the module

Bibliography used during lectures

1	Kamiński M. [red.]	Chromatografia cieczowa	CEEAM, Gdańsk.	2004
2	Witkiewicz Z.	Podstawy chromatografii	WNT, Warszawa.	2005
3	Rosset R., Kołodziejczyk H.	Wspólczesna chromatografia cieczowa	WNT, Warszawa.	2001
4	Narębska A. [red.]	Membrany i membranowe techniki rozdzielania	Wyd. UMK, Toruń.	1997
5	Rautenbach R.	Procesy membranowe	WNT, Warszawa.	1996
6	Berek M., Dressler M., Kubin M., Marcinka K.	Chromatografia żelowa	PWN, Warszawa.	1989
7	Karlberg B., Pacey G. E.	Wstrzykowa analiza przepływowa - dla praktyków	WNT, Warszawa.	1994
8	Trojanowicz M.	Automatyzacja w analizie chemicznej	WNT, Warszawa.	1992
9	Namieśnik J. [red.]	Metody instrumentalne w kontroli zanieczyszczeń środowiska	WPG, Gdańsk.	1992
10	Minczewski J., Chwastowska J., Dybczyński R.	Analiza śladowa. Metody rozdzielania i zagęszczania	WNT, Warszawa.	1973
11	Witkiewicz Z.	Podstawy chromatografii	WNT, Warszawa.	2000
12	Kisza A.	Elektrochemia T.1 Jonika	Warszawa, WNT.	2000
13	Kisza A.	Elektrochemia T.2 Elektrodyka	Warszawa, WNT.	2001
14	Rekść W.	Elektrochemia techniczna: elektrolityczne otrzymywanie metali, gazów technicznych oraz produktów utl	Wyd. Politechnika Poznańska, Poznań.	1990
15	Namieśnik J., Jamrógiewicz Z.	Fizykochemiczne metody kontroli zanieczyszczeń środowiska	WNT, Warszawa.	1998
16	Bandrowski J., Troniewski L.	Destylacja i rektyfikacja	Wyd. Politechnika Śląska, Gliwice.	1996

Bibliography used during classes/laboratories/others

1	Minczewski J., Chwastowska J., Dybczyński R.	Analiza śladowa. Metody rozdzielania i zagęszczania	WNT, Warszawa .	1973
2	Minczewski J., Marczenko Z.	Chemia analityczna	PWN, Warszawa.	1997
3	Namieśnik J., Jamrógiewicz Z., Pilarczyk M., Torres L.	Przygotowanie próbek środowiskowych do analizy	WNT, Warszawa.	2000
4	Namieśnik J., Jamrógiewicz Z.	Fizykochemiczne metody kontroli zanieczyszczeń środowiska	WNT, Warszawa.	1998
5	Kisza A.	Elektrochemia T.1 Jonika	WNT, Warszawa.	2000
6	Kisza A.	Elektrochemia T.2 Elektrodyka	WNT, Warszawa.	2001
7	Rekść W.	Elektrochemia techniczna: elektrolityczne otrzymywanie metali, gazów technicznych oraz produktów utl	Wyd. Politechnika Poznańska, Poznań.	1990
8	Rautenbach R.	Procesy Membranowe	WNT, Warszawa.	1996
9	Narębska A. [red.]	Membrany i membranowe techniki rozdzielania	Wyd. UMK, Toruń.	1997
10	Ościk J.	Adsorpcja	PWN, Warszawa.	1979
11	Bansal, R. Ch., Goyal M.	Adsorpcja na węglu aktywnym	WNT, Warszawa.	2009
12	Bandrowski J., Troniewski L.	Destylacja i rektyfikacja	Wyd. Politechnika Śląska, Gliwice.	1996
13	Witkiewicz Z.	Podstawy chromatografii	WNT, Warszawa.	2000
14	Kamiński M.	Chromatografia cieczowa [red.]	CEEAM, Gdańsk .	2004
15	Rosset R., Kołodziejczyk H.	Współczesna chromatografia cieczowa	WNT, Warszawa.	2001
16	Berek M., Dressler M., Kubin M., Marcinka K.	Chromatografia żelowa	PWN, Warszawa.	1989

Bibliography to self-study

1

Bielicka-Daszkiewicz K., Milczewska K., Voelkel A.

Zastosowanie metod chromatograficznych

Wydaw. Politech. Pozn., Poznań.

2010

Basic requirements in category knowledge/skills/social competences

Formal requirements: Registration for semester II.

Basic requirements in category knowledge: Fundamentals of analytical and physical chemistry as well as physics

Basic requirements in category skills: Practical and manual skills necessary to laboratory experiments carrying out. The use of primary laboratory equipment with the existing Health and Safety rules and Principles of Fire.

Basic requirements in category social competences: The competence of safe use of laboratories equipment on experimental classes. The student can work in a team carrying out experiments.

Module outcomes

MEK	The student who completed the module	Types of classes / teaching methods leading to achieving a given outcome of teaching	Methods of verifying every mentioned outcome of teaching	Relationships with KEK	Relationships with PRK
01	The student has the theoretical knowledge of the techniques of separation and preconcentration of analytes as well as extraction of analytes from environmental samples.	lecture	writing test	K_W07+++ K_W10++	P7S_WG
02	The student can self-reliant carry out experiments using various methods of isolation and enrichment of analytes.	laboratory	writing test	K_U06+++	P7S_UK P7S_UW
03	The student has the fundamental knowledge about the modern methods of traces enrichment.	lecture	writing test	K_W07+++	P7S_WG
04	The student can use from the scientific literature, formulate conclusions and preparing report.	laboratory	writing report	K_U01+++ K_U06+++ K_K01+++ K_K02+++	P7S_KK P7S_KO P7S_UK P7S_UW

Attention: Depending on the epidemic situation, verification of the achieved learning outcomes specified in the study program, in particular credits and examinations at the end of specific classes, can be implemented remotely (real-time meetings).

The syllabus of the module

Sem.	TK	The content	realized in	MEK
2	TK01	Separation and analytes enrichment. Techniques of analytes extraction. Classification of extraction systems. Liquid-liquid extraction. Liquid-solid extraction. Leaching. Solid phase extraction. Supercritical Fluid Extraction. Ion-exchange chromatography. Ion-exchangers. Application of ion-exchange chromatography for separation and concentration of analytes. Thin-layer chromatography (TLC). Gas chromatography (GC) and liquid chromatography (LC). High performance liquid chromatography (HPLC). Coupled techniques (HPLC-FIA- -MS, GC-FIA-MS). Adsorption. Partition and classification of solid adsorbent. Absorption. Precipitation and coprecipitation. Coprecipitation of analytes on supports. Electrolytic precipitation. Volatility of substance. Distillation. Rectification. Mineralization. Electrolysis. Electrophoresis. Dialysis. Electrodialysis. Osmosis. Membrane techniques. Micellar techniques. Crystallization. Filtration. Fluidization. Centrifugation and ultracentrifugation. Sedimentation. Flotation. Molecular sieves. Others techniques of separation and enrichment of analytes. Examples of application of mentioned methods. Apparatus, devices and equipment for implementation of separation processes and preconcentration operation of analytes.	Wykład	MEK01 MEK03
2	TK02	Liquid-liquid extraction. Separation of cobalt(II) ions from cooper(II) ions by extraction of aliphatic ketone in form of rhodanate complexes. Liquid-solid extraction. Extraction of protein from plants resources. Separation and extraction of analyte in the form of metal. Extraction of antimony metal by separation of antimony(III) and tin(II) ions by means of reduction. Liquid-solid adsorption. Adsorption of pioctanine on natural zeolite adsorbent. Precipitation of analyte. Separation of nickle(II) ions from iron(III) ions in presence tartrate by precipitation method. Distillation. Fractional distillation of ammonia. Chromatography. Separatiom of amino acids by chromatogrphic method.	Laboratorium	MEK02 MEK04

The student's effort

The type of classes	The work before classes	The participation in classes	The work after classes
Lecture (sem. 2)		contact hours: 15.00 hours/sem.	complementing/reading through notes: 2.00 hours/sem. Studying the recommended bibliography: 2.00 hours/sem.
Laboratory (sem. 2)	The preparation for a Laboratory: 2.00 hours/sem. The preparation for a test: 10.00 hours/sem.	contact hours: 30.00 hours/sem.	Finishing/Making the report: 6.00 hours/sem.
Advice (sem. 2)	The preparation for Advice: 2.00 hours/sem.	The participation in Advice: 2.00 hours/sem.
Credit (sem. 2)	The preparation for a Credit: 15.00 hours/sem.	The written credit: 2.00 hours/sem.

The way of giving the component module grades and the final grade

The type of classes	The way of giving the final grade
Lecture	A positive result (OW) of the written test during the last lecture. The result 2.0 (ndst) refers to obtain from 0.0 to 49.9% of the total points, 3,0 (dst) refers to obtain from 50,0 to 66,1% of the points, 3,5 (+dst) refers to obtain from 66,2 to 75,1% of the points, 4,0 (db) refers to obtain from 75,2 to 85,1% of the points, 4,5 (+db) refers to obtain from od 85,2 to 94,1% of the points, 5,0 (bdb) refers to obtain from od 94,2 to 100% of the points.
Laboratory	Perform all laboratory experiments. Obtaining positive notes during the laboratories. The note of laboratory (OL) is arithmetic mean of the two test notes and note of preparing report, and then rounded according to the rules given in the Quality Education Faculty
The final grade	The final note (OK) is calculated according to the formula: OK = 0.5•w•OW+ 0.5•w•OL; where: w - factor related to the term pass the laboratory and lecture; w = 1.0 - for positive notes obtained in the first term, w = 0.9 - for notes in the second term, and w = 0.8 - for notes in the third term, and then rounded according to the rules given in the Quality Education Faculty.

Sample problems

Required during the exam/when receiving the credit
(-)

Realized during classes/laboratories/projects
(-)

Others
(-)

Can a student use any teaching aids during the exam/when receiving the credit : no

The contents of the module are associated with the research profile: yes

1	A. Domoń; D. Papciak; E. Sočo	Clean and Tasty Water - Analysis of the Effectiveness of Water Filter Jugs	2024
2	A. Domoń; E. Sočo	Effect of Chemical Modification of the Coal Fly Ash onto Adsorption of Chromium(III) Ions in the Presence of Cobalt(II) Ions in a Single and Binary System	2024
3	J. Kalembkiewicz; A. Kuźniar; B. Papciak; E. Sočo	Zastosowanie materiału krzemionkowego modyfikowanego surfaktantem do immobilizacji moryny	2023
4	M. Azizi; B. Cieniek; A. Domoń; M. Michel; D. Pająk; D. Papciak; E. Sočo	Characteristics of Adsorption/Desorption Process on Dolomite Adsorbent in the Copper(II) Removal from Aqueous Solutions	2023
5	M. Azizi; B. Cieniek; M. Michel; D. Mirosław-Świątek; L. Reczek; E. Sočo	Significance of MnO2 Type and Solution Parameters in Manganese Removal from Water Solution	2023
6	Ł. Byczyński; M. Huta; A. Kuźniar; E. Sočo	Badania produktów sulfonowania kwercetyny	2023
7	A. Domoń; E. Sočo	Immobilizacja metalu ciężkiego z roztworów wodnych na mineralnych sorbentach – dolomitach	2022
8	A. Domoń; J. Konkol; D. Papciak; E. Sočo; B. Tchórzewska-Cieślak; M. Zdeb	Mechanism of Biofilm Formation on Installation Materials and Its Impact on the Quality of Tap Water	2022
9	B. Cieniek; A. Domoń; M. Michel; D. Pająk; D. Papciak; E. Sočo	Characteristics of the Properties of Absodan Plus Sorbent and Its Ability to Remove Phosphates and Chromates from Aqueous Solutions	2022
10	E. Sočo	Zwiększenie zdolności sorpcyjnych układu metal-barwnik z roztworów wodnych poprzez wykorzystanie aktywowanego odpadu przemysłowego	2022
11	J. Kalembkiewicz; E. Pieniążek; J. Pusz; E. Sitarz-Palczak; E. Sočo	Badania właściwości kwercetyny i jej sulfonowych pochodnych w układach z fluoroforem	2022
12	A. Domoń; B. Kupiec; M. Michel; D. Pająk; D. Papciak; E. Sočo	Characterization of the Physical, Chemical, and Adsorption Properties of Coal-Fly-Ash–Hydroxyapatite Composites	2021
13	A. Kuźniar; U. Maciołek; E. Pieniążek; J. Pusz; E. Sočo; E. Woźnicka	Związek kwasu kwercetyno-5’-sulfonowego z jonami sodu. Synteza, właściwości, zastosowanie	2021
14	E. Sočo	Usuwanie rodaminy B z roztworu wodnego za pomocą hydroksyapatytów otrzymanych na bazie lotnego popiołu węglowego	2021
15	J. Kalembkiewicz; B. Papciak; E. Pieniążek; E. Sočo	Stałe związki kompleksowe jonów tytanu(IV) z sulfonową pochodną moryny	2021
16	J. Kalembkiewicz; E. Pieniążek; E. Sočo	Adsorpcja flawonoidów na uporządkowanych mezoporowych materiałach krzemionkowych	2021
17	J. Kalembkiewicz; A. Kuźniar; B. Papciak; J. Pusz; E. Sitarz-Palczak; E. Sočo; E. Woźnicka	Pierwiastki i związki chemiczne	2020
18	J. Kalembkiewicz; A. Kuźniar; E. Pieniążek; E. Sočo; E. Woźnicka	Aktywność biochemiczna sulfonowych pochodnych moryny	2020
19	J. Kalembkiewicz; B. Papciak; E. Pieniążek; J. Pusz; P. Skitał; E. Sočo; L. Zapała	Podstawy chemii	2020
20	J. Kalembkiewicz; D. Pająk; E. Sočo	Multi-component sorption and utilization of solid waste to simultaneous removing basic dye and heavy metal from aqueous system	2020
21	J. Kalembkiewicz; E. Sočo	Characterisation and utilisation of solid waste from coal combustion to modelling of sorption equilibrium in a bi-component system metal-dye	2020
22	J. Kalembkiewicz; E. Sočo	Immobilizing and Removal of Cadmium and Rhodamine B from an Aqueous System by Converting Solid Waste from Poland; Studies of Equilibrium and Kinetic Sorption	2020
23	M. Michel; D. Papciak; E. Sočo	Novel application of mineral by-products obtained from the combustion of bituminous coal-fly ash in chemical engineering	2020
24	J. Kalembkiewicz; E. Sočo	Enhanced sorption capacity of a metal-dye system from water effluents by using activated industrial waste	2019