The aim of studying and bibliography

The main aim of study: The aim of the module is to familiarize the students with the electrochemical analytical methods and the possibilities of their practical use

The general information about the module: Students gain knowledge and skills of the area of theoretical basis and practical application of the electrochemical methods of analysis, as well as contemporary trends in the development of this discipline.

Bibliography required to complete the module

Bibliography used during lectures

1	1. A. Cygański	„Podstawy metod elektroanalitycznych”,	WNT W-wa.	2004
2	W. Szczepaniak	"Metody instrumentalne w analizie chemicznej"	PWN, W-wa .	1997
3	J. Minczewski, Z. Marczenko	„Chemia analityczna"	PWN, W-wa .	1989
4	G.E. Eving	„Metody instrumentalne w analizie chemicznej”	PWN – Warszawa.	1980
5	A Hulanicki	"Współczesna chemia analityczna"	Wydawnictwo Naukowe PWN, Warszawa.	2001
6	K.H. Lubert, K Kalcher	History of Electroanalytical Methods	Electroanalysis, vol. 22, pp. 1937-46, .	2010
7	A. Economou	Recent developments in on-line electrochemical stripping analysis - an overview of the last 12 years	Anal. Chim. Acta, vol. 638, pp. 39-51.	2010

Bibliography used during classes/laboratories/others

1	A. Cygański	„Podstawy metod elektroanalitycznych"	WNT W-wa .	2004
2	J. Minczewski, Z. Marczenko	„Chemia analityczna t. III, Analiza instrumentalna”	PWN, W-wa .	1987

Bibliography to self-study

1	A. Economou	Bismuth-film electrodes: recent developments and potentialities for electroanalysis	Trends in Analytical Chemistry, Vol. 24, No. 4, pp. 334-40.	2005
2	J. Wang	Recent Advances in Stripping Analysis	Fresenius j. Anal. Chem, vol. 337, p. 508-511.	1990
3	Chao Gao ,Xing-Jiu Huang	Review Voltammetric determination of mercury(II)	Trends in Analytical Chemistry vol. 51, pp. 1–12.	2013
4	Lian Zhu, Lili Xu, Baozhen Huang, Ningming Jia, Liang Tan, Shouzhuo Yao Key	Simultaneous determination of Cd(II) and Pb(II) using square waveanodic stripping voltammetry at a gold nanoparticle-graphene-cysteine composite modified bismuth film electrode	Electrochimica Acta, vol. 115, pp. 471– 477.	2014

Basic requirements in category knowledge/skills/social competences

Formal requirements: Student fulfills formal requirements of the knowledge acquired at the first cycle studies.

Basic requirements in category knowledge: Knowledge of the basics of general, physical and analytical chemistry at the level of first cycle studies.

Basic requirements in category skills: Ability to plan and carry out laboratory work as well as to perform chemical calculations

Basic requirements in category social competences: Maturity required in chemist profession and responsibility of working in a team

Module outcomes

MEK	The student who completed the module	Types of classes / teaching methods leading to achieving a given outcome of teaching	Methods of verifying every mentioned outcome of teaching	Relationships with KEK	Relationships with PRK
01	Knows the classification of electrochemical methods of analysis and possibilities of using them in quantitative and qualitative analysis	Lecture	written test	K_W01++ K_W08+++	P7S_WG
02	Has extended knowledge of the theoretical basis of electroanalytical methods, electrochemical systems which are used, types of electrodes and electrode materials	lecture	written test	K_W01++	P7S_WG
03	Has a basic knowledge of voltammetric techniques and possibilities of their application in chemical analysis	lecture	written test	K_W08++	P7S_WG
04	Has a basic knowledge of contemporary development trends and significant attainments in electroanalysis	lecture	oral presentation	K_W09++	P7S_WG
05	Can individually perform analysis using electrochemical techniques, draw up and interpret the results obtained	laboratory	written report	K_U09++ K_U14++	P7S_UO P7S_UW
06	Is able to use the scientific literature, including English language, and prepare an oral presentation	laboratory	realization of registered tasks and oral presentation	K_U01++ K_U06++ K_K01+	P7S_KK P7S_UK P7S_UW
07	Can perform calculations associated with the use of electrochemical methods of analysis	laboratory	written test	K_U09++	P7S_UO P7S_UW

Attention: Depending on the epidemic situation, verification of the achieved learning outcomes specified in the study program, in particular credits and examinations at the end of specific classes, can be implemented remotely (real-time meetings).

The syllabus of the module

Sem.	TK	The content	realized in	MEK
2	TK01	Introduction to electrochemistry and elektrochemical analytical methods. Classification of electroanalytical methods and comparison with other analytical methods with regard to their determination limit.	W01	MEK01
2	TK02	Potentiometry: electrodes and their types, the electrode potential - Nernst equation, the cell, measurement of the cell electromotive force. Ion-selective electrodes (ISE) - classification, construction, potential, properties, applications in chemical analysis. Direct and indirect potentiometry, potentiometric titration (equipment, techniques). Practical application of potentiometry.	W02, L01	MEK02 MEK05 MEK07
2	TK03	Conductometry: basic concepts, theoretical foundations, the types of coductometric techniques, conductometric titration, examples of its application in analytics and in the control of technological processes.	W03, L02	MEK02 MEK05 MEK07
2	TK04	Methods of analysis based on electrolysis in the bulk solution - and coulometry and electro-gravimetry. Basic concepts and mathematical relationships, types of electrode reactions, polarization of the electrodes, overpotential, the electrode reaction potential and external electric potential difference. The ways of electrolysis conducting. Control-potential and control-current coulometry (advantages and disadvantages). The ways of charge determination during electrolysis. Coulometric titration.	W04, L03	MEK02 MEK05 MEK07
2	TK05	Methods of analysis based on the electrolysis in diffusion layer - voltammetry and polarography. Theoretical basis - basic equations, the possibility of application of voltammetric methods in quantitative and qualitative analysis. Kinds of electrodes used in voltammetric techniques. Voltammetric techniques - DC, LSV, CV, AC, pulse - NPP and DPP, square wave - theoretical basis, measurement cirquits, Quantification methods using voltammetric techniques.	W05, W06, L04	MEK03 MEK05 MEK07
2	TK06	Stripping voltammetry techniques as a tool for trace analysis - ASV, CSV, AdsSV. Current trends in the use of stripping techniques, based on a current review of scientific literature	W06, L05	MEK03 MEK05 MEK07
2	TK07	Amperommetry- theoretical basis. Amperometric titration with one or with ndicator electrodes. Dead end point titration. Practical application of amperometric titration.	W07, L06	MEK02 MEK05 MEK07
2	TK08	Contemporary trends in electroanalysis development and application of electrochemical methods of analysis in in the automation of technological processes.	W08, L07	MEK04 MEK06

The student's effort

The type of classes	The work before classes	The participation in classes	The work after classes
Lecture (sem. 2)		contact hours: 15.00 hours/sem.	complementing/reading through notes: 3.00 hours/sem. Studying the recommended bibliography: 3.00 hours/sem.
Laboratory (sem. 2)	The preparation for a Laboratory: 4.00 hours/sem. The preparation for a test: 10.00 hours/sem.	contact hours: 30.00 hours/sem.	Finishing/Making the report: 10.00 hours/sem. Others: 5.00 hours/sem.
Advice (sem. 2)		The participation in Advice: 2.00 hours/sem.
Credit (sem. 2)	The preparation for a Credit: 5.00 hours/sem.	The written credit: 1.00 hours/sem.

The way of giving the component module grades and the final grade

The type of classes	The way of giving the final grade
Lecture	Knowledge of the lecture content is enforced in the form of written tests on laboratory classes
Laboratory	Proper execution of the exercises and elaboration of the results obtained - laboratory reports. Positive mark of each of 4 written tests (wL). The grade calculated on the basis of the number of points scored (50%-59% - 3,0; 60%-69% - 3,5; 70%-79% - 4,0; 80%-89% - 4,5; 90%-100% - 5,0). Positive mark of the oral presentation on a given topic (wP), w - factor related to the credit term (1.0 - a first time, 0.9 - a second time, 0.8 - third time).
The final grade	Final mark (K) is calculated in accordance with the formula: K = 0,8(avL )+ 0,2P, where avL - average mark of 4 written tests (wL).

Sample problems

Required during the exam/when receiving the credit
(-)

Realized during classes/laboratories/projects
(-)

Others
(-)

Can a student use any teaching aids during the exam/when receiving the credit : no

The contents of the module are associated with the research profile: yes

1	A. Domańska; P. Skitał	Elektrolityczne powłoki metaliczne i stopowe jako katalizatory wydzielania wodoru	2023
2	A. Domańska; P. Skitał	Modeling of the Simultaneous Hydrogen Evolution and Cobalt Electrodeposition	2022
3	A. Domańska; P. Skitał	Electrolytic deposition of zinc-nickel alloy coatings with organic addition	2021
4	D. Saletnik; P. Sanecki; P. Skitał	The modeling of simultaneous three metals codeposition investigated by cyclic voltammetry	2020
5	J. Kalembkiewicz; B. Papciak; E. Pieniążek; J. Pusz; P. Skitał; E. Sočo; L. Zapała	Podstawy chemii	2020
6	J. Kalembkiewicz; D. Saletnik; P. Sanecki; P. Skitał	Electrodeposition of nickel from alkaline NH4OH/NH4Cl buffer solutions	2019