The aim of studying and bibliography

The main aim of study: Familiarizing students with the problems of modern catalysis as an interdisciplinary field of science. Demonstration of the importance of catalysis for the development of chemical and petrochemical and related industries, as well as environmental protection.

The general information about the module: The module is carried out in the first semester. It includes 30 hours of lecture and 30 hours laboratory. The module ends with an exam.

Teaching materials: Instrukcje do ćwiczeń laboratoryjnych

others: Ksiązki wskazane jako literatura do wykładu znajdują się w pok. 135 w budynku Wydziału Chemicznego.

Bibliography required to complete the module

Bibliography used during lectures

1	Gupta B.D., Elias A. J.	Basic Organometallic Chemistry	CRC Press.	2010.
2	Hagen J.	Industrial Catalysis. A Practical Approach	Wiley-VHC Verlag GmbH& Co. KGaA.	2006.
3	Grzybowska-Świerkosz B.	Elementy katalizy heterogenicznej	WNT W-wa.	1993.
4	Pruchnik F.	Kataliza homogeniczna	PWN W-wa.	1993
5	Robert Crabtree	The Organometallic Chemistry of the Transition Metals	Wiley .	2009
6		Publikacje z zakresu katalizy (w j. angielskim, o zasięgu międzynarodowym)	.
7	Edited by John Regalbuto	Catalyst preparation. Science and engineering	CSC Press.	2007
8	Arno Behr, Peter Neubert	, Applied Homogenous Catalysis	Wiley-VHC.	2010
9	Farrauto R.J., Dorazio L., Bartholomew C.H.	Introduction to Catalysis and Industrial Catalytic Processes	AIChE Wiley.	2016

Basic requirements in category knowledge/skills/social competences

Formal requirements: Registration for the first semester.

Basic requirements in category knowledge: Basic knowledge of physical, inorganic and organic chemistry and the methods of instrumental analysis.

Basic requirements in category skills: Ability to apply the basic laboratory techniques.

Basic requirements in category social competences: Awareness of the need to work in teams of 2-3 people.

Module outcomes

MEK	The student who completed the module	Types of classes / teaching methods leading to achieving a given outcome of teaching	Methods of verifying every mentioned outcome of teaching	Relationships with KEK	Relationships with PRK
01	Student has knowledge of the clasification of catalysts, taking into consideration of the phase system, their chemical nature and the possibilities of their potential applications in chemical reactions.	lecture, laboratory	written examination, oral test	K_W06+++	P7S_WG
02	Student has basic knowledge of the most important homogeneous and heterogeneous catalysts used in industrial processes.	lecture	written examination	K_W06++	P7S_WG
03	Student has general knowledge of the modern trends in catalysis.	lecture	written examination	K_W09++	P7S_WG
04	Student is able to use scientific literature (in English) for preparation a well-documented written report.	laboratory, implementation of assigned tasks	written report	K_U01++ K_U03+	P7S_UW
05	Student is able to perform experiments on his own using different catalysts, perform product analysis, draw correct conclusions and prepare the final report supporting with scientific literature.	laboratory	written report, observation of performance	K_U03++ K_U14++	P7S_UW
06	Able to work in a team performing catalytic experiments	laboratory	observation of performance	K_K02+	P7S_KO

Attention: Depending on the epidemic situation, verification of the achieved learning outcomes specified in the study program, in particular credits and examinations at the end of specific classes, can be implemented remotely (real-time meetings).

The syllabus of the module

Sem.	TK	The content	realized in	MEK
1	TK01	Introduction to catalysis: historical overview, basic concepts and definitions in the field of catalysis. Classifications catalysts.	W01	MEK01
1	TK02	Acid-base catalysis. Electrophilic and nucleophilic catalysis. Organocatalysis. Phase transfer catalysts.	W02, W03	MEK01 MEK02
1	TK03	Selected problems of coordination chemistry. The basic types of reactions catalyzed by transition metal complexes.	W04-W05	MEK02
1	TK04	Catalysts of hydrogenation, hydrocyanation, hydrosilylation, hydroformylation and other reactions with carbon monoxide participation.	W06-W07	MEK01
1	TK05	Catalysts of polymerization, olefin isomerization and oligomerization.	W08	MEK01
1	TK06	Metathesis catalysts. Palladium catalyzed cross-coupling reactions. Copper catalyzed cross-coupling reactions.Other transition metals in coipling reactions. Catalysts for oxidation reactions.Principles asymmetric catalysis.	W09-W10	MEK03
1	TK07	Heterogeneous catalysts - general clasifications, methods of preparation and characterization. Industrial catalysis. Catalysis in environmental protection.	W11-W15	MEK02
1	TK08	Experiments with the selected homogeneous and heterogeneous catalysts, including chiral catalysts.	L01-L05	MEK04 MEK05 MEK06
1	TK09	Synthesis of the selected homogeneous and heterogeneous catalysts and their characterization.	L01-L05	MEK04 MEK05 MEK06

The student's effort

The type of classes	The work before classes	The participation in classes	The work after classes
Lecture (sem. 1)		contact hours: 30.00 hours/sem.	complementing/reading through notes: 3.00 hours/sem. Studying the recommended bibliography: 10.00 hours/sem.
Laboratory (sem. 1)	The preparation for a Laboratory: 10.00 hours/sem. The preparation for a test: 25.00 hours/sem.	contact hours: 30.00 hours/sem.	Finishing/Making the report: 25.00 hours/sem.
Advice (sem. 1)	The preparation for Advice: 2.00 hours/sem.	The participation in Advice: 15.00 hours/sem.
Exam (sem. 1)	The preparation for an Exam: 25.00 hours/sem.	The written exam: 2.00 hours/sem.

The way of giving the component module grades and the final grade

The type of classes	The way of giving the final grade
Lecture	Positive mark of the written exam.
Laboratory	Passed all practical tasks, final reports and theoretical tests.
The final grade	The final grade (K): K = 0.5E + 0.5L: where E, L - positive grade of the exam and laboratory, respectively; w – a coefficient, w = 1.0 for the first exam, 0.9 for the second exam

Sample problems

Required during the exam/when receiving the credit
(-)

Realized during classes/laboratories/projects
(-)

Others
(-)

Can a student use any teaching aids during the exam/when receiving the credit : no

The contents of the module are associated with the research profile: yes

1	K. Bester; A. Bukowska; W. Bukowski; A. Kawka; M. Pytel	Salophen chromium(III) complexes functionalized with pyridinium salts as catalysts for carbon dioxide cycloaddition to epoxides	2024
2	K. Bester; A. Bukowska; W. Bukowski; M. Drajewicz; K. Dychtoń; R. Ostatek; P. Szałański	Sposób wytwarzania salofenowego kompleksu chromu(III)	2024
3	K. Bester; A. Bukowska; W. Bukowski; S. Flaga	Reactive Polymer Composite Microparticles Based on Glycidyl Methacrylate and Magnetite Nanoparticles	2024
4	K. Bester; A. Bukowska; W. Bukowski; M. Drajewicz; K. Dychtoń; R. Ostatek; P. Szałański	Ligand salphenowy oraz sposób syntezy tego ligandu salphenowego	2023
5	K. Bester; W. Bukowski; M. Kaczmarek; D. Tomczyk	Electrocatalytic Properties of Ni(II) Schiff Base Complex Polymer Films	2022
6	K. Bester; W. Bukowski; P. Seliger; D. Tomczyk	The Influence of Electrolyte Type on Kinetics of Redox Processes in the Polymer Films of Ni(II) Salen-Type Complexes	2022
7	K. Bester; A. Bukowska; W. Bukowski	Homogeniczny katalizator chromowy, sposób jego wytwarzania, układ katalityczny zawierający ten katalizator oraz zastosowanie tego układu katalitycznego	2021
8	K. Bester; A. Bukowska; W. Bukowski; M. Pytel	Polymer Beads Decorated with Dendritic Systems as Supports for A3 Coupling Catalysts	2021
9	K. Bester; A. Bukowska; W. Bukowski; M. Pytel; A. Sobota	Copolymerization of Phthalic Anhydride with Epoxides Catalyzed by Amine-Bis(Phenolate) Chromium(III) Complexes	2021
10	K. Bester; A. Bukowska; W. Bukowski	Homogeniczny katalizator chromowy, sposób jego wytwarzania, układ katalityczny zawierający ten katalizator oraz zatosowanie tego układu katalitycznego	2019
11	K. Bester; W. Bukowski; D. Tomczyk	Kinetics of Redox Processes in the Polymer Films of Ni(II) Salen Type Complexes	2019