The aim of studying and bibliography

The main aim of study: The aim of the module is to provide knowledge and acquire of skills in the scope of influence of various degradation processes and flammability of polymers on the properties of plastics.

The general information about the module: The module is implemented in the second semester. It includes 15 hours of lecture and 15 hours laboratory. The module does not end with an exam.

Teaching materials: Instrukcje do ćwiczeń laboratoryjnych

others: Aktualne artykuły z czasopisma "Polimery", "Tworzywa sztuczne" oraz obowizujące Ustawy i Rozporządze

Bibliography required to complete the module

Bibliography used during lectures

1	J. Kijeński, A.K. Błędzki	Odzysk i recykling materiałów polimerowych	Wyd. Naukowe PWN SA, Warszawa.	2011
2	J. Pączkowski (praca zbiorowa)	Fotochemia polimerów teoria i zastosowanie	Wyd. Uniw. M. Kopernika, Toruń.	2003
3	G. Janowska, W. Przygocki, A. Włochowicz	Palność polimerów i materiałów polimerowych	WNT, Warszawa.	2007
4	J. W. Nicholson	Chemia polimerów	WNT. Warszawa.	1996
5	Z. Florjańczyk	Chemia polimerów, tom III	Oficyna Wyd. Polit. Warszawskiej, Warszawa.	2001
6	J. Pielichowski, A. Puszyński	Technologia tworzyw sztucznych	WNT, Warszawa.	2003
7	Aleksander Prociak, Gabriel Rokicki, Joanna Ryszkowska	Materiały poliuretanowe	Wydaw.Nauk.PWN, Warszawa.	2014

Bibliography used during classes/laboratories/others

1	J. Pielichowski, A. Puszyński	Chemia polimerów	Wyd. Oświatowe Fosze, Rzeszów.	2012
2	A. Błędzki	Recykling materiałów polimerowych	Wyd. Naukowo-Techniczne, Warszawa.	1997
3	W Przygocki	Metody fizyczne badań polimerów	PWN, Warszawa.	1990

Bibliography to self-study

1	M. Żenkiewicz	Adhezja i modyfikowanie warswy wierzchniej tworzyw wielkocząsteczkowych	WNT Warszawa.	2000
2	I. Gruin	Materiały polimerowe	PWN Warszawa.	2003
3	Z. Witkiewicz, J. Hetper	Chromatografia gazowa	WNT Warszawa.	2009

Basic requirements in category knowledge/skills/social competences

Formal requirements: Registration for the semester

Basic requirements in category knowledge: Student knows the basics of chemical reaction mechanisms and of polymer chemistry. He has the preliminary knowledge of polymer technology.

Basic requirements in category skills: Student is able to plan and perform laboratory work by himself.

Basic requirements in category social competences: Student demonstrates social maturity required in the profession of chemist. He understands the responsibility, which is necessary to work in the chemical laboratory.

Module outcomes

MEK	The student who completed the module	Types of classes / teaching methods leading to achieving a given outcome of teaching	Methods of verifying every mentioned outcome of teaching	Relationships with KEK	Relationships with PRK
01	Student knows the basic principles of the environment protection related to processing of waste disposal of selected plastics	lecture	written test	K_W04+	P7S_WG
02	Student can perform an experiment of the degradation of a plastic using the knowledge of the different methods of decomposition of polymeric materials	laboratory, lecture	observation of performance, written report, written test	K_W12+ K_U01++ K_U09+	P7S_UO P7S_UW P7S_WG
03	Student has knowledge of the resistance of polymers submitted to various chemical, physical and biological factors.	lecture, laboratory	written test	K_W09+ K_U10+	P7S_UW P7S_WG
04	Stydent understands the need to verify the acquired knowledge on the degradation of polymeric with regard to apperance of new polymeric materials on the market	educational discussion	observation of performance	K_K01+	P7S_KK

Attention: Depending on the epidemic situation, verification of the achieved learning outcomes specified in the study program, in particular credits and examinations at the end of specific classes, can be implemented remotely (real-time meetings).

The syllabus of the module

Sem.	TK	The content	realized in	MEK
2	TK01	Fundamentals of polymer degradation processes. Plastics stabilisators. Chemical degradation. Radiation degradation. Depolymerization. Photodegradation. Biodegradation. Thermal degradation. Basics of thermal degradation kinetics. Flammability of polymeric materials. Natural aging of polymers.	W01-W15	MEK01 MEK02 MEK03 MEK04
2	TK02	Selected laboratory exercises with the following topics: Study on the kinetics of hydrolytic degradation of polyamide 6, Depolymerisation of thermoplasts, Study on the process of hydrolytic degradation of poly (ethylene terephthalate) (PET), Study on the thermal degradation of selected polymer with the use of thermogravimetric analysis TGA.	L1-L3	MEK02 MEK04

The student's effort

The type of classes	The work before classes	The participation in classes	The work after classes
Lecture (sem. 2)		contact hours: 15.00 hours/sem.	complementing/reading through notes: 3.00 hours/sem. Studying the recommended bibliography: 5.00 hours/sem.
Laboratory (sem. 2)	The preparation for a Laboratory: 10.00 hours/sem.	contact hours: 15.00 hours/sem.	Finishing/Making the report: 3.00 hours/sem.
Advice (sem. 2)	The preparation for Advice: 1.00 hours/sem.	The participation in Advice: 1.00 hours/sem.
Credit (sem. 2)	The preparation for a Credit: 5.00 hours/sem.	The written credit: 2.00 hours/sem.

The way of giving the component module grades and the final grade

The type of classes	The way of giving the final grade
Lecture	Written test of the issues presented in the lecture. The range of % points suit the assessments: 50 - 59,9% rating 3.0, 60 - 69,9% rating 3.5, 70 - 79,9% rating 4.0, 80 - 89,9% rating 4.5, over 89,9% rating 5.0
Laboratory	Student must perform all of the planed experiments, prepare and pass written reports, pass tests from theoretical information connected with exepriments.
The final grade	Final grade (K): K = 0,5 w L + 0,5 w Z; where: L, Z - positive evaluation of the lab and lecture; w - factor related to the time of credit, w= 1.0 first term, w = 0.9 second term , w = 0.8 third term.

Sample problems

Required during the exam/when receiving the credit
(-)

Realized during classes/laboratories/projects
(-)

Others
(-)

Can a student use any teaching aids during the exam/when receiving the credit : no

The contents of the module are associated with the research profile: yes

1	J. Bieniaś; Ł. Byczyński; D. Czachor-Jadacka; M. Droździel-Jurkiewic; M. Kisiel; B. Mossety-Leszczak; G. Pietruszewska; M. Włodarska; W. Zając	Nonterminal liquid crystalline epoxy resins as structurally ordered low Tg thermosets with potential as smart polymers	2024
2	Ł. Byczyński; D. Czachor-Jadacka; M. Kisiel; B. Mossety-Leszczak; B. Pilch-Pitera; K. Pojnar; M. Walczak; J. Wojturska	Poliuretanowy lakier proszkowy oraz sposób wytwarzania poliuretanowego lakieru proszkowego	2024
3	Ł. Byczyński; E. Ciszkowicz; D. Czachor-Jadacka; M. Kisiel; B. Mossety-Leszczak; B. Pilch-Pitera; M. Walczak; J. Wojturska	Wodna dyspersja kationomerów uretanowo-akrylowych, sposób wytwarzania wodnej dyspersji kationomerów uretanowo-akrylowych oraz sposób wytwarzania fotoutwardzalnej powłoki z wykorzystaniem tej wodnej dyspersji	2024
4	Ł. Byczyński; E. Godek; E. Grządka; M. Kosińska-Pezda; U. Maciołek; A. Nowicka	Colloidal and Thermal Stability of Three-Component Hybrid Materials Containing Clay Mineral, Polysaccharide and Surfactant	2024
5	Ł. Byczyński; M. Kisiel; M. Szołyga	Poly(urethane-acrylate) cationomer coatings with increased hydrophobicity and reduced flammability	2024
6	Ł. Byczyński; M. Huta; A. Kuźniar; E. Sočo	Badania produktów sulfonowania kwercetyny	2023
7	Ł. Byczyński; M. Kosińska-Pezda; E. Woźnicka; L. Zapała; W. Zapała	Synteza oraz badania składu i właściwości związków: 3-hydroksyflawonu, chryzyny oraz sulfonowych pochodnych chryzyny i kwercetyny z jonami Mn(II)	2023
8	Ł. Byczyński; M. Kosińska-Pezda; U. Maciołek; L. Zapała	Study of the thermal behavior, evolved gas analysis and temperature diffraction patterns of new light lanthanide complexes with niflumic acid	2023
9	Ł. Byczyński; P. Król; M. Sochacka-Piętal	Hydrophilic polyurethane films containing gastrodin as potential temporary biomaterials	2023
10	Ł. Byczyński; A. Kramek; B. Pilch-Pitera; K. Pojnar; M. Walczak; W. Zając	Polyacrylate resins containing fluoroalkyl groups for powder clear coatings	2022
11	Ł. Byczyński; B. Pilch-Pitera; J. Prejzner	Kompozycja wodorozcieńczalnego tuszu do cyfrowego druku na tekstyliach, sposób jego otrzymywania oraz sposób wykonywania nadruku tą kompozycją	2022
12	Ł. Byczyński; D. Czachor-Jadacka; B. Pilch-Pitera; J. Wojturska; J. Wojturski; P. Wrona	Farba proszkowa	2022
13	Ł. Byczyński; K. Król-Morkisz; T. Majka; K. Pielichowska; K. Pielichowski	The effect of functionalized hydroxyapatite on the thermal degradation behaviour and flammability of polyoxymethylene copolymer	2022
14	Ł. Byczyński; M. Dutkiewicz; R. Januszewski; S. Rojewski	Polyurethane high-solids coatings modified with silicon-containing functionalized cyclotriphosphazene	2022
15	Ł. Byczyński; P. Król; B. Pilch-Pitera; J. Wojturska	Sposób wytwarzania blokowanych poliizocyjanianów do poliuretanowych powłok proszkowych	2022
16	Ł. Byczyński; D. Czachor-Jadacka; M. Kisiel; B. Pilch-Pitera; A. Zioło	Hydrophobic polyurethane powder clear coatings with lower curing temperature: Study on the synthesis of new blocked polyisocyanates	2021
17	Ł. Byczyński; E. Ciszkowicz; M. Kosińska-Pezda; K. Lecka-Szlachta; U. Maciołek; E. Woźnicka; L. Zapała; W. Zapała	Green synthesis of niflumic acid complexes with some transition metal ions (Mn(II), Fe(III), Co(II), Ni(II), Cu(II) and Zn(II)). Spectroscopic, thermoanalytical and antibacterial studies	2021
18	Ł. Byczyński; M. Kosińska-Pezda; U. Maciołek; E. Woźnicka; L. Zapała; W. Zapała	Thermal study, temperature diffraction patterns and evolved gas analysis during pyrolysis and oxidative decomposition of novel ternary complexes of light lanthanides with mefenamic acid and 1,10-phenanthroline	2021
19	Ł. Byczyński; P. Król; B. Pilch-Pitera; J. Wojturska	Blokowane poliizocyjaniany, ich zastosowanie oraz poliuretanowe lakiery proszkowe	2021
20	Ł. Byczyński; P. Król; B. Pilch-Pitera; J. Wojturska	Blokowane poliizocyjaniany, sposób ich wytwarzania i zastosowanie	2021
21	Ł. Byczyński; A. Czerniecka-Kubicka; W. Frącz; M. Pyda; V. Sedlarik; A. Szyszkowska; I. Zarzyka	Hybrid nanobiocomposites based on poly(3-hydroxybutyrate) – characterization, thermal and mechanical properties	2020
22	Ł. Byczyński; M. Dutkiewicz; R. Januszewski; B. Pilch-Pitera; P. Wrona	Epoxy coatings with increased hydrophobicity modified by isocyanurate containing siloxane	2020
23	Ł. Byczyński; Z. Florjańczyk; M. Heneczkowski; R. Oliwa; B. Pilch-Pitera; A. Plichta; G. Rokicki; J. Wadas	Synthesis and characterization of one-component, moisture curing polyurethane adhesive based on Rokopol D2002	2020
24	A. Bobrowski; Ł. Byczyński; S. Cukrowicz; B. Grabowska; K. Kaczmarska; S. Żymankowska-Kumon	Thermoanalytical studies (TG–DTG–DSC, Py–GC/MS) of sodium carboxymethyl starch with different degrees of substitution	2019
25	Ł. Byczyński; A. Czerniecka-Kubicka; K. Gancarczyk; M. Pyda; V. Sedlarik; A. Szyszkowska; I. Zarzyka	Linear polyurethanes with imidazoquinazoline rings: preparation and properties evaluation	2019
26	Ł. Byczyński; D. Czachor; Ł. Florczak; K. Kowalczyk; E. Pavlova; B. Pilch-Pitera; J. Wojturski	Conductive polyurethane-based powder clear coatings modified with carbon nanotubes	2019
27	Ł. Byczyński; M. Chutkowski; E. Ciszkowicz; M. Kosińska; K. Lecka-Szlachta; E. Woźnicka; L. Zapała; W. Zapała	Comparison of spectral and thermal properties and antibacterial activity of new binary and ternary complexes of Sm(III), Eu(III) and Gd (III) ions with N-phenylanthranilic acid and 1,10-phenanthroline	2019