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Physical chemistry of polymers

Some basic information about the module

Cycle of education: 2022/2023

The name of the faculty organization unit: The faculty Chemistry

The name of the field of study: Chemical Technology

The area of study: technical sciences

The profile of studing:

The level of study: second degree study

Type of study: full time

discipline specialities : Technology of medicinal products, Chemical analysis in industry and environment , Organic and polymer technology, Polymer materials engineering, Product and ecological process engineering

The degree after graduating from university: Master of Science (MSc)

The name of the module department : Department of Technology and Materials Chemistry

The code of the module: 1354

The module status: mandatory for the speciality Organic and polymer technology

The position in the studies teaching programme: sem: 2 / W30 L45 / 5 ECTS / E

The language of the lecture: English

The name of the coordinator: Beata Mossety-Leszczak, DSc, PhD, Eng.

office hours of the coordinator: Środa – godz. 10.30 - 12.00 Czwartek – godz. 10.00 - 11.30

semester 2: Małgorzata Walczak, PhD, Eng.

semester 2: Barbara Pilch-Pitera, DSc, PhD

The aim of studying and bibliography

The main aim of study: Aquiring knowledge on the basic physicochemical description of polymers, required for understanding properties of polymers and polymeric materials as well as methods of their analysis and characterization

The general information about the module: The modulus provides information on physicochemical properties of polymers and polymeric materials

Teaching materials: Przeźrocza do wykładu

Bibliography required to complete the module
Bibliography used during lectures
1 H. Galina Fizykochemia polimerów Oficyna Wodawnicza Politechniki Rzeszowskiej. 1998
2 H. Galina (pod red.) Fizyka materiałów polimerowych. Makrocząsteczki i ich układy WNT Warszawa . 2008
Bibliography used during classes/laboratories/others
1 E. Hałasa, A. Żmihorska-Gotfryd Chemia fizyczna polimerów. Laboratorium Wyd. Polit. Rzeszowskiej, Rzeszów. 1990

Basic requirements in category knowledge/skills/social competences

Formal requirements: Completed modulus on physical chemistry

Basic requirements in category knowledge: Knowledge of principles of physical chemistry, including thermodynamics. Recommended knowledge on polymer chemistry and technology

Basic requirements in category skills: Has a laboratory skill in instrumental analysis

Basic requirements in category social competences: Capable of working in team. Knows safety and fire protection regulations in chemical laboratory

Module outcomes

MEK The student who completed the module Types of classes / teaching methods leading to achieving a given outcome of teaching Methods of verifying every mentioned outcome of teaching Relationships with KEK Relationships with PRK
01 Have an extended knowledge on the physical properties of polymers, both in condensed state and in solution lacture, laboratory written and oral test, visual monitoring, written report K_W10+++
P7S_WG
02 Has a well grounded and broaden knowlkedge on properties and methods of interpretation of polymer behaviour lecture, laboratory written and oral test, oral verifications, written report. K_W12++
P7S_WG
03 Gained knowledge on analysis and solving research problems related to interpretation of results on properties of polymers and polymeric materials lecture, laboratory oral and written test, written report K_U09++
K_U12++
P7S_UO
P7S_UW
04 While identifying and solving research problems is capable of integrating the knowledge in chemistry, physics, physical chemistry and specialized subjects. lecture, laboratory oral and written test, knowledge verification K_U11+++
P7S_UW
05 Understands the need of broadening the knowledge on new facts relating structure with properties in polymer science lecture skill observation K_K01++
P7S_KK
06 Has the ability to work in a team for efficient performing of tasks in polymer science laboratory skill observation K_K02+
P7S_KO

Attention: Depending on the epidemic situation, verification of the achieved learning outcomes specified in the study program, in particular credits and examinations at the end of specific classes, can be implemented remotely (real-time meetings).

The syllabus of the module

Sem. TK The content realized in MEK
2 TK01 Specific, physical properties of polymers and polymer systems W01 MEK01
2 TK02 Relations concerning molecular mass distributions and linking mechanisms of polymer synthesis and the type of molecular mass distribution W01, W02, L01 MEK03
2 TK03 Sizes of makromolecules in solutions and in bulk, properties of polymer solutions and blends W03, W04, L02 MEK01 MEK05
2 TK04 Hydrodynamics of polymer solutions W05, L02 MEK03
2 TK05 Elements of polymer viscoelasticity, rheological models W06, W07, L07 MEK04
2 TK06 Moduli-temperature relationships; glass transition, polymer structure vs. glass transition temperature W08, W09, L05 MEK02 MEK03
2 TK07 Rubber elasticity W10, L03 MEK02 MEK05
2 TK08 Polymer in viscoelastic region, effect of entanglements, reptation model of stress relaxation W11, L07 MEK02 MEK04
2 TK09 Crystalline state of polymers W12, L04 MEK04 MEK05 MEK06
2 TK10 Specialty polymer, liquid crystallinity and polymers W13, W14 MEK05
2 TK11 Surface properties of polymers W15 MEK04 MEK06

The student's effort

The type of classes The work before classes The participation in classes The work after classes
Lecture (sem. 2) contact hours: 30.00 hours/sem.
complementing/reading through notes: 5.00 hours/sem.
Others: 1.00 hours/sem.
Laboratory (sem. 2) The preparation for a Laboratory: 5.00 hours/sem.
The preparation for a test: 10.00 hours/sem.
contact hours: 45.00 hours/sem.
Finishing/Making the report: 5.00 hours/sem.
Advice (sem. 2) The participation in Advice: 2.00 hours/sem.
Exam (sem. 2) The preparation for an Exam: 30.00 hours/sem.
The written exam: 1.00 hours/sem.
Others: 5.00 hours/sem.

The way of giving the component module grades and the final grade

The type of classes The way of giving the final grade
Lecture Positive mark of the written exam in the form of a test - W1. The grading scale is provided on the examination sheet. The evaluation depends on the percentage obtained as follows: 50,1-60%: 3.0 60,1-70%: 3.5 70,1-80%: 4.0 80,1-90%: 4.5 90,1-100%: 5.0 The mark from the second term - 0.9 of the mark obtained.
Laboratory Student must perform all of the planed experiments, prepare and pass written reports, pass tests from theoretical information connected with laboratory lessons. Average mark from test, written report from each exercise – W2. Weighting factor: w = 1,0 first term, w = 0,9 second term.
The final grade Final mark: W = w 0,5 W1 + w 0,5 W2; w - weighting factor: w = 1,0 first term, w = 0,9 second term.

Sample problems

Required during the exam/when receiving the credit
(-)

Realized during classes/laboratories/projects
(-)

Others
(-)

Can a student use any teaching aids during the exam/when receiving the credit : no

The contents of the module are associated with the research profile: yes

1 J. Bieniaś; Ł. Byczyński; D. Czachor-Jadacka; M. Droździel-Jurkiewic; M. Kisiel; B. Mossety-Leszczak; G. Pietruszewska; M. Włodarska; W. Zając Nonterminal liquid crystalline epoxy resins as structurally ordered low Tg thermosets with potential as smart polymers 2024
2 K. Awsiuk; N. Janiszewska; B. Mossety-Leszczak; J. Raczkowska; A. Strachota; B. Strachota; M. Walczak; A. Zioło Synthesis and Morphology Characteristics of New Highly Branched Polycaprolactone PCL 2024
3 M. Kisiel; B. Mossety-Leszczak The Effect of Nonterminal Liquid Crystalline Epoxy Resin Structure and Curing Agents on the Glass Transition of Polymer Networks 2024
4 M. Kisiel; B. Mossety-Leszczak; L. Okrasa; M. Włodarska Modification of the Dielectric and Thermal Properties of Organic Frameworks Based on Nonterminal Epoxy Liquid Crystal with Silicon Dioxide and Titanium Dioxide 2024
5 M. Kisiel; B. Mossety-Leszczak; W. Zając Advancements in The Cross-Linking and Morphology of Liquid Crystals 2024
6 Ł. Byczyński; D. Czachor-Jadacka; M. Kisiel; B. Mossety-Leszczak; B. Pilch-Pitera; K. Pojnar; M. Walczak; J. Wojturska Poliuretanowy lakier proszkowy oraz sposób wytwarzania poliuretanowego lakieru proszkowego 2024
7 Ł. Byczyński; E. Ciszkowicz; D. Czachor-Jadacka; M. Kisiel; B. Mossety-Leszczak; B. Pilch-Pitera; M. Walczak; J. Wojturska Wodna dyspersja kationomerów uretanowo-akrylowych, sposób wytwarzania wodnej dyspersji kationomerów uretanowo-akrylowych oraz sposób wytwarzania fotoutwardzalnej powłoki z wykorzystaniem tej wodnej dyspersji 2024
8 M. Kisiel; B. Mossety-Leszczak; L. Okrasa; M. Włodarska; W. Zając Changes in molecular relaxations and network properties of a triaromatic liquid crystal epoxy resin with nonterminal functional groups 2023
9 J. Karaś; M. Kisiel; B. Mossety-Leszczak; B. Pilch-Pitera; M. Włodarska; W. Zając The application of liquid crystalline epoxy resin for forming hybrid powder coatings 2022
10 K. Byś; J. Hodan; B. Mossety-Leszczak; E. Pavlova; A. Strachota; B. Strachota Self-Healing and Super-Elastomeric PolyMEA-co-SMA Nanocomposites Crosslinked by Clay Platelets 2022
11 M. Kisiel; B. Mossety-Leszczak Liquid Crystalline Polymers 2022
12 B. Mossety-Leszczak; M. Włodarska DFT Studies of Selected Epoxies with Mesogenic Units–Impact of Molecular Structure on Electro-Optical Response 2021
13 K. Byś; B. Mossety-Leszczak; E. Pavlova; M. Steinhart; A. Strachota; B. Strachota; W. Zając Novel Tough and Transparent Ultra-Extensible Nanocomposite Elastomers Based on Poly(2-methoxyethylacrylate) and Their Switching between Plasto-Elasticity and Viscoelasticity 2021
14 M. Kisiel; B. Mossety-Leszczak; A. Strachota; B. Strachota Achieving structural anisotropy of liquid crystalline epoxy by manipulation with crosslinking parameters 2021
15 M. Kisiel; B. Mossety-Leszczak Development in liquid crystalline epoxy resins and composites – A review 2020
16 M. Marchel; B. Mossety-Leszczak; M. Walczak Maize (Zea mays) reaction in response to rubber rag additive into the soil 2020
17 S. Horodecka; D. Kaňková; B. Mossety-Leszczak; M. Netopilík; M. Šlouf; A. Strachota; B. Strachota; M. Vyroubalová; Z. Walterová; A. Zhigunov Low-Temperature Meltable Elastomers Based on Linear Polydimethylsiloxane Chains Alpha, Omega-Terminated with Mesogenic Groups as Physical Crosslinkers: A Passive Smart Material with Potential as Viscoelastic Coupling. Part I: Synthesis and Phase Behavior 2020
18 S. Horodecka; D. Kaňková; B. Mossety-Leszczak; M. Netopilík; M. Šlouf; A. Strachota; M. Vyroubalová; A. Zhigunov Meltable copolymeric elastomers based on polydimethylsiloxane with multiplets of pendant liquid-crystalline groups as physical crosslinker: A self-healing structural material with a potential for smart applications. 2020
19 S. Horodecka; M. Kisiel; B. Mossety-Leszczak; M. Šlouf; A. Strachota; B. Strachota Low-Temperature-Meltable Elastomers Based on Linear Polydimethylsiloxane Chains Alpha, Omega-Terminated with Mesogenic Groups as Physical Crosslinker: A Passive Smart Material with Potential as Viscoelastic Coupling. Part II—Viscoelastic and Rheological Properties 2020
20 A. Frańczak; M. Kisiel; B. Mossety-Leszczak; D. Szczęch Quantitative analysis of the polymeric blends 2019
21 N. Buszta; M. Kisiel; J. Lechowicz; B. Mossety-Leszczak; R. Ostatek; M. Włodarska Analysis of curing reaction of liquid-crystalline epoxy compositions by using temperature-modulated DSC TOPEM (R) 2019