The aim of studying and bibliography

The main aim of study: Gaining knowledge of the physico-chemical and technological aspects of the production of modern materials by chemical and physical modyfication of polymeric materials

The general information about the module: The module consists of a lecture, which will be presented the newest methods of polymer modification and their importance for the production of new materials for engineering, construction, electronics, agriculture and medicine. The knowledge obtained by students during the lecture will be extended within laboratory classes and students will acquire skills in chemistry and technology of modification of selected polymers.

Bibliography required to complete the module

Bibliography used during lectures

1	Florjańczyk Z., Penczek S	Chemia polimerów, tom 3	Oficyna Wydawnicza Politechniki Warszawskiej .	1998
2	Flizikowski J	Rozdrabnianie tworzyw sztucznych	Wyd. ATR, Bydgoszcz.	1998
3	Żenkiewicz M.	Adhezja i modyfikowanie warstwy wierzchniej tworzyw wielkocząsteczkowych	WNT, Warszawa.	2000
4	Przygocki W., Włochowicz A.	Fizyka polimerów	PWN, Warszawa.	2001
5	Rabek J.F.	Polimery. Otrzymywanie, metody badawcze, zastosowanie	PWN, Warszawa.	2013

Bibliography used during classes/laboratories/others

1

Pielichowskij., Puszyński A.

Technologia tworzyw sztucznych

WNT, Warzszawa.

2003

Bibliography to self-study

1	Rabek J.F.	Współczesna wiedza o polimerach T1 i T2	PWN, Warszawa.	2017
2	Prociak A., Rokicki G., Ryszkowska J.	Materiały poliuretanowe	PWN, Warszawa.	2016

Basic requirements in category knowledge/skills/social competences

Formal requirements: Registration for the third semester

Basic requirements in category knowledge: Knowledge of mechanisms and basic methods of polymer production. Knowledge of properties and uses of most commonly used polymeric materials: polyolefins, PVC, condensation resins

Basic requirements in category skills: Ability to work in a chemical laboratory dedicated to polymer synthesis

Basic requirements in category social competences: Responsibility, working with health and safety legislation and the ability to work in a chemical laboratory

Module outcomes

MEK	The student who completed the module	Types of classes / teaching methods leading to achieving a given outcome of teaching	Methods of verifying every mentioned outcome of teaching	Relationships with KEK	Relationships with PRK
01	has knowledge of basic methods of chemical and physical modification of polymers and their importance in material engineering	lecture	pass written test	K_W03+ K_W07+++ K_U08++ K_U19++ K_K01++	P6S_KK P6S_UU P6S_UW P6S_WG
02	has knowledge of the importance of modifying polymers for obtaining materials with controlled properties	laboratory, lecture	test, written report	K_W03++ K_W07++ K_U06++ K_U08++ K_U19+ K_K01+	P6S_KK P6S_UU P6S_UW P6S_WG
03	they can calculate the amount of substances which are necessary to obtain a modified polymer and can analyze the results of selected physicochemical properties of polymers	laboratory	test, written report	K_U06+ K_U08+ K_U19+ K_K01+	P6S_KK P6S_UU P6S_UW
04	is able to select standardized measuring methods for analyzing selected application properties of modified polymers	lecture, laboratory	test, written report	K_U06+++ K_U08++ K_K01+	P6S_KK P6S_UW

Attention: Depending on the epidemic situation, verification of the achieved learning outcomes specified in the study program, in particular credits and examinations at the end of specific classes, can be implemented remotely (real-time meetings).

The syllabus of the module

Sem.	TK	The content	realized in	MEK
6	TK01	Modification of polymers as a method of obtaining new materials. Chemical modification: block copolymers, alternating and graft copolymers with vinyl and diene copolymers. Ionomers. Physical modification: examples of physical modification, types and properties of polymer fillers, types of fibrous fillers, plasticisation of polymeric materials. Nanomaterials obtained by physical modification. Methods of surface modification of polymeric materials. Trends in modyfication of polymers.Polymer modification in the paint and varnish industry.	W01 - W15	MEK01 MEK02 MEK04
6	TK02	Chemical modification of polymers towards increasing hydrophobicity	L01	MEK01 MEK03
6	TK03	Synthesis and physical modification of high-solid coatings	L02	MEK02 MEK03
6	TK04	Preparation and characterization of polymer superabsorbent	L03	MEK02
6	TK05	Synthesis of polyurethane cationomer	L04	MEK03 MEK04

The student's effort

The type of classes	The work before classes	The participation in classes	The work after classes
Lecture (sem. 6)	The preparation for a test: 2.00 hours/sem.	contact hours: 15.00 hours/sem.	complementing/reading through notes: 3.00 hours/sem. Studying the recommended bibliography: 15.00 hours/sem. Others: 2.00 hours/sem.
Laboratory (sem. 6)	The preparation for a Laboratory: 10.00 hours/sem. The preparation for a test: 10.00 hours/sem.	contact hours: 20.00 hours/sem.	Finishing/Making the report: 4.00 hours/sem.
Advice (sem. 6)	The preparation for Advice: 2.00 hours/sem.	The participation in Advice: 2.00 hours/sem.
Credit (sem. 6)	The preparation for a Credit: 2.00 hours/sem.	The written credit: 1.00 hours/sem.

The way of giving the component module grades and the final grade

The type of classes	The way of giving the final grade
Lecture	Pass written test. The test can take place outside the university using information technology Rating: Q1
Laboratory	Pass reports and written test. The test can take place outside the university using information technology. Rating: Q2
The final grade	Q=0,5(Q1+Q2)

Sample problems

Required during the exam/when receiving the credit
(-)

Realized during classes/laboratories/projects
(-)

Others
(-)

Can a student use any teaching aids during the exam/when receiving the credit : no

The contents of the module are associated with the research profile: yes

1	B. Pilch-Pitera; K. Pojnar	Correlation between the Chemical Structure of (Meth)Acrylic Monomers and the Properties of Powder Clear Coatings Based on the Polyacrylate Resins	2024
2	D. Czachor-Jadacka; B. Pilch-Pitera	Blokowane poliizocyjaniany o zwiększonej funkcyjności oraz sposób wytwarzania blokowanych poliizocyjanianów o zwiększonej funkcyjności	2024
3	J. Bieniaś; Ł. Byczyński; D. Czachor-Jadacka; M. Droździel-Jurkiewic; M. Kisiel; B. Mossety-Leszczak; G. Pietruszewska; M. Włodarska; W. Zając	Nonterminal liquid crystalline epoxy resins as structurally ordered low Tg thermosets with potential as smart polymers	2024
4	K. Biller; D. Czachor-Jadacka; B. Pilch-Pitera	Recent development advances in bio-based powder coatings: a review	2024
5	M. Kędzierski; M. Kisiel; B. Pilch-Pitera; K. Pojnar; A. Zioło	UV-cured powder transparent coatings based on oligo(meth)acrylic resins	2024
6	R. Patil; B. Pilch-Pitera; K. Pojnar	Progress in the development of acrylic resin-based powder coatings – an overview	2024
7	Ł. Byczyński; D. Czachor-Jadacka; M. Kisiel; B. Mossety-Leszczak; B. Pilch-Pitera; K. Pojnar; M. Walczak; J. Wojturska	Poliuretanowy lakier proszkowy oraz sposób wytwarzania poliuretanowego lakieru proszkowego	2024
8	Ł. Byczyński; E. Ciszkowicz; D. Czachor-Jadacka; M. Kisiel; B. Mossety-Leszczak; B. Pilch-Pitera; M. Walczak; J. Wojturska	Wodna dyspersja kationomerów uretanowo-akrylowych, sposób wytwarzania wodnej dyspersji kationomerów uretanowo-akrylowych oraz sposób wytwarzania fotoutwardzalnej powłoki z wykorzystaniem tej wodnej dyspersji	2024
9	Ł. Byczyński; E. Godek; E. Grządka; M. Kosińska-Pezda; U. Maciołek; A. Nowicka	Colloidal and Thermal Stability of Three-Component Hybrid Materials Containing Clay Mineral, Polysaccharide and Surfactant	2024
10	Ł. Byczyński; M. Kisiel; M. Szołyga	Poly(urethane-acrylate) cationomer coatings with increased hydrophobicity and reduced flammability	2024
11	Ł. Florczak; B. Pilch-Pitera; K. Pojnar; N. Roś	Low-temperature powder paint modified with graphene oxide	2024
12	D. Czachor-Jadacka; B. Pilch-Pitera	Niskotemperaturowe powłoki proszkowe otwierają nowe możliwości	2023
13	D. Czachor-Jadacka; T. Jomin; M. Kisiel; B. Pilch-Pitera	Polyurethane powder coatings with low curing temperature: Research on the effect of chemical structure of crosslinking agent on the properties of coatings	2023
14	Ł. Byczyński; M. Huta; A. Kuźniar; E. Sočo	Badania produktów sulfonowania kwercetyny	2023
15	Ł. Byczyński; M. Kosińska-Pezda; E. Woźnicka; L. Zapała; W. Zapała	Synteza oraz badania składu i właściwości związków: 3-hydroksyflawonu, chryzyny oraz sulfonowych pochodnych chryzyny i kwercetyny z jonami Mn(II)	2023
16	Ł. Byczyński; M. Kosińska-Pezda; U. Maciołek; L. Zapała	Study of the thermal behavior, evolved gas analysis and temperature diffraction patterns of new light lanthanide complexes with niflumic acid	2023
17	Ł. Byczyński; P. Król; M. Sochacka-Piętal	Hydrophilic polyurethane films containing gastrodin as potential temporary biomaterials	2023
18	B. Pilch-Pitera	Studia podyplomowe \"Farby i lakiery proszkowe – technologia wytwarzania, aplikacja, zastosowanie\"	2022
19	D. Czachor-Jadacka; B. Pilch-Pitera; K. Pojnar	Lakiery proszkowe na bazie modyfikowanych żywic akrylowych	2022
20	D. Czachor-Jadacka; Ł. Florczak; B. Pilch-Pitera; K. Pojnar	Właściwości ochronne niskotemperaturowych poliuretanowych lakierów proszkowych na bazie żywic akrylowych	2022
21	J. Karaś; M. Kisiel; B. Mossety-Leszczak; B. Pilch-Pitera; M. Włodarska; W. Zając	The application of liquid crystalline epoxy resin for forming hybrid powder coatings	2022
22	Ł. Byczyński; A. Kramek; B. Pilch-Pitera; K. Pojnar; M. Walczak; W. Zając	Polyacrylate resins containing fluoroalkyl groups for powder clear coatings	2022
23	Ł. Byczyński; B. Pilch-Pitera; J. Prejzner	Kompozycja wodorozcieńczalnego tuszu do cyfrowego druku na tekstyliach, sposób jego otrzymywania oraz sposób wykonywania nadruku tą kompozycją	2022
24	Ł. Byczyński; D. Czachor-Jadacka; B. Pilch-Pitera; J. Wojturska; J. Wojturski; P. Wrona	Farba proszkowa	2022
25	Ł. Byczyński; K. Król-Morkisz; T. Majka; K. Pielichowska; K. Pielichowski	The effect of functionalized hydroxyapatite on the thermal degradation behaviour and flammability of polyoxymethylene copolymer	2022
26	Ł. Byczyński; M. Dutkiewicz; R. Januszewski; S. Rojewski	Polyurethane high-solids coatings modified with silicon-containing functionalized cyclotriphosphazene	2022
27	Ł. Byczyński; P. Król; B. Pilch-Pitera; J. Wojturska	Sposób wytwarzania blokowanych poliizocyjanianów do poliuretanowych powłok proszkowych	2022
28	A. Bielaska; M. Bosek; M. Kracik; T. Matłosz; M. Nawrocki; B. Pilch-Pitera	Sposób wykonywania trwałego nadruku struktur przestrzennych na płaskich powierzchniach	2021
29	D. Czachor-Jadacka; B. Pilch-Pitera	Progress in development of UV curable powder coatings	2021
30	D. Czachor-Jadacka; J. Gumieniak; M. Kisiel; B. Pilch-Pitera	Hydrophobic UV-Curable Powder Clear Coatings: Study on the Synthesis of New Crosslinking Agents Based on Raw Materials Derived from Renewable Sources	2021
31	D. Czachor-Jadacka; Ł. Florczak; B. Pilch-Pitera	Właściwości ochronne niskotemperaturowych poliuretanowych lakierów proszkowych o zwiększonej hydrofobowości	2021
32	Ł. Byczyński; D. Czachor-Jadacka; M. Kisiel; B. Pilch-Pitera; A. Zioło	Hydrophobic polyurethane powder clear coatings with lower curing temperature: Study on the synthesis of new blocked polyisocyanates	2021
33	Ł. Byczyński; E. Ciszkowicz; M. Kosińska-Pezda; K. Lecka-Szlachta; U. Maciołek; E. Woźnicka; L. Zapała; W. Zapała	Green synthesis of niflumic acid complexes with some transition metal ions (Mn(II), Fe(III), Co(II), Ni(II), Cu(II) and Zn(II)). Spectroscopic, thermoanalytical and antibacterial studies	2021
34	Ł. Byczyński; M. Kosińska-Pezda; U. Maciołek; E. Woźnicka; L. Zapała; W. Zapała	Thermal study, temperature diffraction patterns and evolved gas analysis during pyrolysis and oxidative decomposition of novel ternary complexes of light lanthanides with mefenamic acid and 1,10-phenanthroline	2021
35	Ł. Byczyński; P. Król; B. Pilch-Pitera; J. Wojturska	Blokowane poliizocyjaniany, ich zastosowanie oraz poliuretanowe lakiery proszkowe	2021
36	Ł. Byczyński; P. Król; B. Pilch-Pitera; J. Wojturska	Blokowane poliizocyjaniany, sposób ich wytwarzania i zastosowanie	2021
37	M. Dębowski; Z. Florjańczyk; A. Iuliano; S. Kowalczyk; M. Mazurek-Budzyńska; P. Parzuchowski; B. Pilch-Pitera; A. Plichta; G. Rokicki; D. Wołosz	Polycarbonate-based polyurethane - attractive materials for adhesives, binders and sealants production	2020
38	Ł. Byczyński; A. Czerniecka-Kubicka; W. Frącz; M. Pyda; V. Sedlarik; A. Szyszkowska; I. Zarzyka	Hybrid nanobiocomposites based on poly(3-hydroxybutyrate) – characterization, thermal and mechanical properties	2020
39	Ł. Byczyński; M. Dutkiewicz; R. Januszewski; B. Pilch-Pitera; P. Wrona	Epoxy coatings with increased hydrophobicity modified by isocyanurate containing siloxane	2020
40	Ł. Byczyński; Z. Florjańczyk; M. Heneczkowski; R. Oliwa; B. Pilch-Pitera; A. Plichta; G. Rokicki; J. Wadas	Synthesis and characterization of one-component, moisture curing polyurethane adhesive based on Rokopol D2002	2020
41	A. Bobrowski; Ł. Byczyński; S. Cukrowicz; B. Grabowska; K. Kaczmarska; S. Żymankowska-Kumon	Thermoanalytical studies (TG–DTG–DSC, Py–GC/MS) of sodium carboxymethyl starch with different degrees of substitution	2019
42	Ł. Byczyński; A. Czerniecka-Kubicka; K. Gancarczyk; M. Pyda; V. Sedlarik; A. Szyszkowska; I. Zarzyka	Linear polyurethanes with imidazoquinazoline rings: preparation and properties evaluation	2019
43	Ł. Byczyński; D. Czachor; Ł. Florczak; K. Kowalczyk; E. Pavlova; B. Pilch-Pitera; J. Wojturski	Conductive polyurethane-based powder clear coatings modified with carbon nanotubes	2019
44	Ł. Byczyński; M. Chutkowski; E. Ciszkowicz; M. Kosińska; K. Lecka-Szlachta; E. Woźnicka; L. Zapała; W. Zapała	Comparison of spectral and thermal properties and antibacterial activity of new binary and ternary complexes of Sm(III), Eu(III) and Gd (III) ions with N-phenylanthranilic acid and 1,10-phenanthroline	2019